Synthesis and Electrochemical Properties of CuFeO2 as Negative Electrodes for Sodium-Ion Batteries

Yuhki Yui; Yoko Ono; Masahiko Hayashi; Jiro Nakamura

doi:doi:10.11648/j.ajpc.20150402.11

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Synthesis and Electrochemical Properties of CuFeO2 as Negative Electrodes for Sodium-Ion Batteries

Yuhki Yui, Yoko Ono, Masahiko Hayashi, Jiro Nakamura

Published in American Journal of Physical Chemistry (Volume 4, Issue 2)

Received: 29 March 2015 Accepted: 3 April 2015 Published: 14 April 2015

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Abstract

This paper investigates the electrochemical properties of CuFeO2 prepared by using a malate precursor method as negative electrodes for sodium-ion batteries. In the voltage range of 0.01 to 3.0 V, the oxide calcined at 750C shows a poor cycle property of 27 mAh/g at 10 cycles, although it exhibits the large first discharge capacity of 579 mAh/g. The cycle property is improved to up to 122 mAh/g at 10 cycles by employing a cycle condition with the voltage range of 0.01 to 1.5 V. The results suggest that the sodium-ion insertion/extraction mechanism in CuFeO2 would involve valence changes of Fe ions in the oxide from the Fe3+ state to Fe0 state in the discharge process and from Fe0 to Fe3+ in the charge process.

Published in	American Journal of Physical Chemistry (Volume 4, Issue 2)
DOI	10.11648/j.ajpc.20150402.11
Page(s)	16-20
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2015. Published by Science Publishing Group

Keywords

Sodium-Ion Battery, Negative Electrode, CuFeO2

References

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APA Style

Yuhki Yui, Yoko Ono, Masahiko Hayashi, Jiro Nakamura. (2015). Synthesis and Electrochemical Properties of CuFeO2 as Negative Electrodes for Sodium-Ion Batteries. American Journal of Physical Chemistry, 4(2), 16-20. https://doi.org/10.11648/j.ajpc.20150402.11

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ACS Style

Yuhki Yui; Yoko Ono; Masahiko Hayashi; Jiro Nakamura. Synthesis and Electrochemical Properties of CuFeO2 as Negative Electrodes for Sodium-Ion Batteries. Am. J. Phys. Chem. 2015, 4(2), 16-20. doi: 10.11648/j.ajpc.20150402.11

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AMA Style

Yuhki Yui, Yoko Ono, Masahiko Hayashi, Jiro Nakamura. Synthesis and Electrochemical Properties of CuFeO2 as Negative Electrodes for Sodium-Ion Batteries. Am J Phys Chem. 2015;4(2):16-20. doi: 10.11648/j.ajpc.20150402.11

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@article{10.11648/j.ajpc.20150402.11,
  author = {Yuhki Yui and Yoko Ono and Masahiko Hayashi and Jiro Nakamura},
  title = {Synthesis and Electrochemical Properties of CuFeO2 as Negative Electrodes for Sodium-Ion Batteries},
  journal = {American Journal of Physical Chemistry},
  volume = {4},
  number = {2},
  pages = {16-20},
  doi = {10.11648/j.ajpc.20150402.11},
  url = {https://doi.org/10.11648/j.ajpc.20150402.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpc.20150402.11},
  abstract = {This paper investigates the electrochemical properties of CuFeO2 prepared by using a malate precursor method as negative electrodes for sodium-ion batteries. In the voltage range of 0.01 to 3.0 V, the oxide calcined at 750C shows a poor cycle property of 27 mAh/g at 10 cycles, although it exhibits the large first discharge capacity of 579 mAh/g. The cycle property is improved to up to 122 mAh/g at 10 cycles by employing a cycle condition with the voltage range of 0.01 to 1.5 V. The results suggest that the sodium-ion insertion/extraction mechanism in CuFeO2 would involve valence changes of Fe ions in the oxide from the Fe3+ state to Fe0 state in the discharge process and from Fe0 to Fe3+ in the charge process.},
 year = {2015}
}

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TY  - JOUR
T1  - Synthesis and Electrochemical Properties of CuFeO2 as Negative Electrodes for Sodium-Ion Batteries
AU  - Yuhki Yui
AU  - Yoko Ono
AU  - Masahiko Hayashi
AU  - Jiro Nakamura
Y1  - 2015/04/14
PY  - 2015
N1  - https://doi.org/10.11648/j.ajpc.20150402.11
DO  - 10.11648/j.ajpc.20150402.11
T2  - American Journal of Physical Chemistry
JF  - American Journal of Physical Chemistry
JO  - American Journal of Physical Chemistry
SP  - 16
EP  - 20
PB  - Science Publishing Group
SN  - 2327-2449
UR  - https://doi.org/10.11648/j.ajpc.20150402.11
AB  - This paper investigates the electrochemical properties of CuFeO2 prepared by using a malate precursor method as negative electrodes for sodium-ion batteries. In the voltage range of 0.01 to 3.0 V, the oxide calcined at 750C shows a poor cycle property of 27 mAh/g at 10 cycles, although it exhibits the large first discharge capacity of 579 mAh/g. The cycle property is improved to up to 122 mAh/g at 10 cycles by employing a cycle condition with the voltage range of 0.01 to 1.5 V. The results suggest that the sodium-ion insertion/extraction mechanism in CuFeO2 would involve valence changes of Fe ions in the oxide from the Fe3+ state to Fe0 state in the discharge process and from Fe0 to Fe3+ in the charge process.
VL  - 4
IS  - 2
ER  -

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Author Information

Yuhki Yui

Energy and Environment Systems Laboratories, NTT Corporation, Kanagawa 243-0198, Japan
Yoko Ono

Energy and Environment Systems Laboratories, NTT Corporation, Kanagawa 243-0198, Japan
Masahiko Hayashi

Energy and Environment Systems Laboratories, NTT Corporation, Kanagawa 243-0198, Japan
Jiro Nakamura

Energy and Environment Systems Laboratories, NTT Corporation, Kanagawa 243-0198, Japan

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Plain Text BibTeX RIS

APA Style

Yuhki Yui, Yoko Ono, Masahiko Hayashi, Jiro Nakamura. (2015). Synthesis and Electrochemical Properties of CuFeO2 as Negative Electrodes for Sodium-Ion Batteries. American Journal of Physical Chemistry, 4(2), 16-20. https://doi.org/10.11648/j.ajpc.20150402.11

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ACS Style

Yuhki Yui; Yoko Ono; Masahiko Hayashi; Jiro Nakamura. Synthesis and Electrochemical Properties of CuFeO2 as Negative Electrodes for Sodium-Ion Batteries. Am. J. Phys. Chem. 2015, 4(2), 16-20. doi: 10.11648/j.ajpc.20150402.11

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AMA Style

Yuhki Yui, Yoko Ono, Masahiko Hayashi, Jiro Nakamura. Synthesis and Electrochemical Properties of CuFeO2 as Negative Electrodes for Sodium-Ion Batteries. Am J Phys Chem. 2015;4(2):16-20. doi: 10.11648/j.ajpc.20150402.11

Copy | Download

@article{10.11648/j.ajpc.20150402.11,
  author = {Yuhki Yui and Yoko Ono and Masahiko Hayashi and Jiro Nakamura},
  title = {Synthesis and Electrochemical Properties of CuFeO2 as Negative Electrodes for Sodium-Ion Batteries},
  journal = {American Journal of Physical Chemistry},
  volume = {4},
  number = {2},
  pages = {16-20},
  doi = {10.11648/j.ajpc.20150402.11},
  url = {https://doi.org/10.11648/j.ajpc.20150402.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpc.20150402.11},
  abstract = {This paper investigates the electrochemical properties of CuFeO2 prepared by using a malate precursor method as negative electrodes for sodium-ion batteries. In the voltage range of 0.01 to 3.0 V, the oxide calcined at 750C shows a poor cycle property of 27 mAh/g at 10 cycles, although it exhibits the large first discharge capacity of 579 mAh/g. The cycle property is improved to up to 122 mAh/g at 10 cycles by employing a cycle condition with the voltage range of 0.01 to 1.5 V. The results suggest that the sodium-ion insertion/extraction mechanism in CuFeO2 would involve valence changes of Fe ions in the oxide from the Fe3+ state to Fe0 state in the discharge process and from Fe0 to Fe3+ in the charge process.},
 year = {2015}
}

Copy | Download

TY  - JOUR
T1  - Synthesis and Electrochemical Properties of CuFeO2 as Negative Electrodes for Sodium-Ion Batteries
AU  - Yuhki Yui
AU  - Yoko Ono
AU  - Masahiko Hayashi
AU  - Jiro Nakamura
Y1  - 2015/04/14
PY  - 2015
N1  - https://doi.org/10.11648/j.ajpc.20150402.11
DO  - 10.11648/j.ajpc.20150402.11
T2  - American Journal of Physical Chemistry
JF  - American Journal of Physical Chemistry
JO  - American Journal of Physical Chemistry
SP  - 16
EP  - 20
PB  - Science Publishing Group
SN  - 2327-2449
UR  - https://doi.org/10.11648/j.ajpc.20150402.11
AB  - This paper investigates the electrochemical properties of CuFeO2 prepared by using a malate precursor method as negative electrodes for sodium-ion batteries. In the voltage range of 0.01 to 3.0 V, the oxide calcined at 750C shows a poor cycle property of 27 mAh/g at 10 cycles, although it exhibits the large first discharge capacity of 579 mAh/g. The cycle property is improved to up to 122 mAh/g at 10 cycles by employing a cycle condition with the voltage range of 0.01 to 1.5 V. The results suggest that the sodium-ion insertion/extraction mechanism in CuFeO2 would involve valence changes of Fe ions in the oxide from the Fe3+ state to Fe0 state in the discharge process and from Fe0 to Fe3+ in the charge process.
VL  - 4
IS  - 2
ER  -

Copy | Download